4,4'-METHYLENEBIS(2,6-DIMETHYLPHENOL)

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Quality manufacturer supply 4,4'-METHYLENEBIS(2,6-DIMETHYLPHENOL) 5384-21-4 in stock with high standard

  • Molecular Formula: C17H20O2
  • Molecular Weight: 256.345
  • Appearance/Colour: Crystalline powder 
  • Vapor Pressure: 0Pa at 25℃ 
  • Melting Point: 176 °C 
  • Boiling Point: 414.7 °C at 760 mmHg 
  • PKA: 10.21±0.10(Predicted) 
  • Flash Point: 193.6 °C 
  • PSA: 40.46000 
  • Density: 1.11 g/cm3 
  • LogP: 3.92220 

5384-21-4 Relevant articles

Cycloaddition of bis-cyclohexa-2,4-dienones: Synthesis of novel carbocycles

Singh, Deepak,Deota, Pradeep T.

, p. 292 - 300 (2013)

Syntheses of novel carbocycles (4) and (...

Oxidative acetylation of tetramethyl bisphenol-F

Deota, Pradeep T.,Parmar, Hemant S.,Valodkar, Vaibhav B.,Upadhyay, Piyush R.,Sahoo

, p. 673 - 678 (2006)

Oxidative acetylation of tetramethyl bis...

Synthesis, oxidation and crosslinking of tetramethyl bisphenol F (TMBPF)-based polymers for oxygen/nitrogen gas separations

Sundell, Benjamin J.,Shaver, Andrew T.,Liu, Qiang,Nebipasagil, Ali,Pisipati, Priya,Mecham, Sue J.,Riffle, Judy S.,Freeman, Benny D.,McGrath, James E.

, p. 5623 - 5634 (2014)

Amorphous, high glass transition, crossl...

Development of Transition-Metal-Free Lewis Acid-Initiated Double Arylation of Aldehyde: A Facile Approach Towards the Total Synthesis of Anti-Breast-Cancer Agent

Singh, Sanjay,Mahato, Rina,Sharma, Pragya,Yadav, Naveen,Vodnala, Nagaraju,Kumar Hazra, Chinmoy

supporting information, (2022/02/19)

This work describes a mild and robust do...

Unusual transformation of 4-hydroxy/methoxybenzylic alcohols via C[sbnd]C ipso-substitution reaction using proton-exchanged montmorillonite as media

Chen, Dongyin,Chen, Xuan,Dong, Zezhong,Jiang, Nan,Li, Fei,Yun, Yangfang,Zhou, Yu

supporting information, (2020/11/12)

We present here proton-exchanged montmor...

Eco-friendly Solvent-free Route to Alkyl- and Aryl-Bisphenols Catalyzed by Perchloric Acid-Silica

Deota, Pradeep T.,Singh, Deepak

, p. 1 - 7 (2020/07/21)

-

Surface-accessible detection units in self-immolative polymers enable translation of selective molecular detection events into amplified responses in macroscopic, solid-state plastics

Yeung, Kimy,Kim, Hyungwoo,Mohapatra, Hemakesh,Phillips, Scott T.

supporting information, p. 5324 - 5327 (2015/05/13)

This Communication describes a strategy ...

5384-21-4 Process route

sodium 2-naphtholate
875-83-2

sodium 2-naphtholate

(Z)-N-nitroso-2,6-dimethyl-4-(methylaminomethyl)phenol
90466-00-5

(Z)-N-nitroso-2,6-dimethyl-4-(methylaminomethyl)phenol

2-Methoxynaphthalene
93-04-9

2-Methoxynaphthalene

bis(4-hydroxy-3,5-dimethylphenyl)methane
5384-21-4

bis(4-hydroxy-3,5-dimethylphenyl)methane

1-(4-hydroxy-3,5-dimethylbenzyl)-2-naphthol

1-(4-hydroxy-3,5-dimethylbenzyl)-2-naphthol

1-(4-hydroxy-3,5-dimethylbenzyl)-2-methoxynaphthalene

1-(4-hydroxy-3,5-dimethylbenzyl)-2-methoxynaphthalene

Conditions
Conditions Yield
With potassium hydroxide; In water; at 100 ℃; for 2h; Further byproducts given;
161 mg
17 mg
67.0 mg
4,4'-(oxybis(methylene))bis(2,6-dimethylphenol)
71655-87-3

4,4'-(oxybis(methylene))bis(2,6-dimethylphenol)

bis(4-hydroxy-3,5-dimethylphenyl)methane
5384-21-4

bis(4-hydroxy-3,5-dimethylphenyl)methane

Conditions
Conditions Yield
With proton exchanged montmorillonite; In dichloromethane; at 25 ℃; for 0.25h;
86%

5384-21-4 Upstream products

  • 50-00-0
    50-00-0

    formaldehyd

  • 576-26-1
    576-26-1

    2.6-dimethylphenol

  • 64-17-5
    64-17-5

    ethanol

  • 45952-56-5
    45952-56-5

    3,5-dimethyl-4-hydroxybenzyl bromide

5384-21-4 Downstream products

  • 30128-02-0
    30128-02-0

    2,6-dimethyl-[1,4]benzoquinone-4-(4-hydroxy-phenylimine)

  • 59079-37-7
    59079-37-7

    2,6,2',6'-tetramethyl-4,4'-methanediyl-bis-cyclohexanol

  • 1125-51-5
    1125-51-5

    dibromo-3,4 dimethylphenol-2,6

  • 16271-22-0
    16271-22-0

    4,4'-Dimethoxy-3,3',5,5'-tetramethyldiphenylmethane

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